Wei, Qiang et al. published their research in ACS Catalysis in 2020 | CAS: 61150-57-0

2-Bromo-4-fluorobenzylbromide (cas: 61150-57-0) belongs to organobromine compounds. Most organobromine compounds, like most organohalide compounds, are relatively nonpolar. When the molecular ion is detected, the bromine and chlorine isotope patterns are very distinct, but caution is to be exercised for certain mixed chlorinated/brominated compounds, which can look similar to homohalogen patterns.Recommanded Product: 2-Bromo-4-fluorobenzylbromide

Enantioselective Access to γ-All-Carbon Quaternary Center-Containing Cyclohexanones by Palladium-Catalyzed Desymmetrization was written by Wei, Qiang;Cai, Jinhui;Hu, Xu-Dong;Zhao, Jing;Cong, Hengjiang;Zheng, Chao;Liu, Wen-Bo. And the article was included in ACS Catalysis in 2020.Recommanded Product: 2-Bromo-4-fluorobenzylbromide This article mentions the following:

An efficient desymmetrization of γ-quaternary carbon-containing cyclohexanones using readily available Pd/(S)-tBuPhox and benzyl amine as dual catalysts is reported. The development of the reaction, exploration on the substrate scope, and studies on the reaction mechanism. The intramol. coupling reaction leads to the formation of bicyclo[3.3.1]nonanones with a quaternary carbon bridgehead in synthetically useful yields (up to 98%) with high enantioselectivities (up to 98:2 er) and good functional group tolerance (>30 examples). Significantly, aryl and alkenyl bromides, as well as less reactive triflates are all compatible substrates for this process. The synthetic versatility of this strategy is demonstrated by scale-up synthesis and diverse transformations of the products into valuable building blocks, including quaternary center-containing dihydronaphthalenes, ring-fused indole and lactone, tetralones, and 6,6,5-tricycles. Mechanistic studies by computational calculations provide insights into the role of benzyl amine in accelerating the reaction rate and enhancing the enantioselectivities. In the experiment, the researchers used many compounds, for example, 2-Bromo-4-fluorobenzylbromide (cas: 61150-57-0Recommanded Product: 2-Bromo-4-fluorobenzylbromide).

2-Bromo-4-fluorobenzylbromide (cas: 61150-57-0) belongs to organobromine compounds. Most organobromine compounds, like most organohalide compounds, are relatively nonpolar. When the molecular ion is detected, the bromine and chlorine isotope patterns are very distinct, but caution is to be exercised for certain mixed chlorinated/brominated compounds, which can look similar to homohalogen patterns.Recommanded Product: 2-Bromo-4-fluorobenzylbromide

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary