Substituent effects on the mass spectra of substituted phenyl acetates was written by Gamble, A. A.;Gilbert, J. R.;Tillett, J. G.. And the article was included in Organic Mass Spectrometry in 1971.Category: bromides-buliding-blocks This article mentions the following:
The mass spectra of a series of meta- and para-substituted phenyl acetates were examined Substituent effects were correlated with Δ(AP-IP) values (AP = appearance potential; IP = ionization potential) and by using the Harrison and Chin approach. The bond-cleavage and rearrangement reactions of Ph acetates are compared with the corresponding reactions of acetanilides and the differences attributed to the degree of transmission of polar effects in the 2 systems. In the experiment, the researchers used many compounds, for example, 3-Bromophenyl acetate (cas: 35065-86-2Category: bromides-buliding-blocks).
3-Bromophenyl acetate (cas: 35065-86-2) belongs to organobromine compounds. Bromine is more electronegative than carbon (2.9 vs 2.5). Consequently, the carbon in a carbon–bromine bond is electrophilic, i.e. alkyl bromides are alkylating agents. Commercially available organobromine pharmaceuticals include the vasodilator nicergoline, the sedative brotizolam, the anticancer agent pipobroman, and the antiseptic merbromin. Category: bromides-buliding-blocks
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary