Wang, Ping et al. published their research in Acta Crystallographica, Section C: Crystal Structure Communications in 2009 | CAS: 6515-58-8

3-(Bromomethyl)benzoic acid (cas: 6515-58-8) belongs to organobromine compounds. A variety of minor organobromine compounds are found in nature, but none are biosynthesized or required by mammals. Organobromine compounds have fallen under increased scrutiny for their environmental impact. Many of the alkyl bromine derivatives are excellent alkylating agents since bromides are good leaving groups. Tribromides, like tetrabutylammonium tribromide, are used as a solid source of bromine. N-bromosuccimide (NBS) is used for the selective bromination of allylic bonds.Category: bromides-buliding-blocks

Two bicyclic dinuclear complexes generated from 3,3′-[1,3,4-thiadiazole-2,5-diyldi(thiomethylene)]dibenzoic acid (L) and dimethylformamide (DMF): [Cu(L)(DMF)]2 and [Zn(L)(DMF)]2 was written by Wang, Ping;Ma, Jian-Ping;Li, Xiao-Yan;Huang, Ru-Qi;Dong, Yu-Bin. And the article was included in Acta Crystallographica, Section C: Crystal Structure Communications in 2009.Category: bromides-buliding-blocks This article mentions the following:

A new 1,3,4-thiadiazole bridging ligand, 3,3′-[1,3,4-thiadiazole-2,5-diyldi(thiomethylene)]dibenzoic acid (L), was used to create the novel isomorphous complexes bis{μ-3,3′-[1,3,4-thiadiazole-2,5-diyldi(thiomethylene)]dibenzoato}bis[(DMF)copper(II)], [Cu2(C18H12N2O4S3)2(C3H7NO)2], (I), and bis{μ-3,3′-[1,3,4-thiadiazole-2,5-diyldi(thiomethylene)]dibenzoato}bis[(DMF)zinc(II)], [Zn2(C18H12N2O4S3)2(C3H7NO)2], (II). Crystallog. data are given. Both exist as centrosym. bicyclic dimers constructed through the syn-syn bidentate bridging mode of the carboxylate groups. The two rings share a metal-metal bond and each of the metal atoms possesses a square-pyramidal geometry capped by the DMF mol. The 1,3,4-thiadiazole rings play a critical role in the formation of a π-π stacking system that expands the dimensionality of the structure from zero to one. The TGA of (I) indicates decomposition of the coordinated ligands on heating. Compared with the fluorescence of L in the solid state, the fluorescence intensity of (II) is relatively enhanced with a slight red shift, while that of (I) is quenched. In the experiment, the researchers used many compounds, for example, 3-(Bromomethyl)benzoic acid (cas: 6515-58-8Category: bromides-buliding-blocks).

3-(Bromomethyl)benzoic acid (cas: 6515-58-8) belongs to organobromine compounds. A variety of minor organobromine compounds are found in nature, but none are biosynthesized or required by mammals. Organobromine compounds have fallen under increased scrutiny for their environmental impact. Many of the alkyl bromine derivatives are excellent alkylating agents since bromides are good leaving groups. Tribromides, like tetrabutylammonium tribromide, are used as a solid source of bromine. N-bromosuccimide (NBS) is used for the selective bromination of allylic bonds.Category: bromides-buliding-blocks

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary