Synthesis of two photolabile benzyl manganese derivatives incorporating a geometrically inaccessible radical trap was written by Keana, John F. W.;Pou, Sovitj. And the article was included in Organic Preparations and Procedures International in 1989.Quality Control of 3-(Bromomethyl)benzoic acid This article mentions the following:
Synthesis of 2 title compounds I and II are described. Oxidation of 3,5-(BrCH2)2C6H3CO2Me with (Bu4N)2Cr2O7 in CHCl3 gave 31% monoformylated derivative which on 2 stepwise condensations with Me3CNHOH and NaMn(CO)5 gave I. Chlorination of 3-BrCH2C6H4CO2H with SOCl2 followed by 2 stepwise condensations with 2,2,6,6-tetramethyl-4-amino-1-piperidinyloxy and MeMn(CO)5 gave II. In the experiment, the researchers used many compounds, for example, 3-(Bromomethyl)benzoic acid (cas: 6515-58-8Quality Control of 3-(Bromomethyl)benzoic acid).
3-(Bromomethyl)benzoic acid (cas: 6515-58-8) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. alpha-Bromoesters are employed in the Reformatsky reaction for the synthesis of beta-hydroxyesters. Many of the alkyl bromine derivatives are excellent alkylating agents since bromides are good leaving groups. Tribromides, like tetrabutylammonium tribromide, are used as a solid source of bromine. N-bromosuccimide (NBS) is used for the selective bromination of allylic bonds.Quality Control of 3-(Bromomethyl)benzoic acid
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary