Leech, Matthew C.; Petti, Alessia; Tanbouza, Nour; Mastrodonato, Andrea; Goodall, Iain C. A.; Ollevier, Thierry; Dobbs, Adrian P.; Lam, Kevin published an article in 2021. The article was titled 《Anodic Oxidation of Aminotetrazoles: A Mild and Safe Route to Isocyanides》, and you may find the article in Organic Letters.Quality Control of Tris(4-bromophenyl)amine The information in the text is summarized as follows:
A new electrochem. method for the preparation of isocyanides RN+C- (R = octyl, cyclohexylmethyl, 4-tert-butylphenyl, thiophen-2-ylmethyl, etc.) from easily accessible aminotetrazole derivatives I has been developed, which tolerates an unprecedented range of functional groups. The use of chem., rather than electrochem., oxidation to afford isocyanides was also demonstrated, which provides access to these compounds for those without electrosynthesis equipment. The practicality of scale-up using flow electrochem. has been demonstrated, in addition to the possibility of using electrochem. generated isocyanides in further reactions.Tris(4-bromophenyl)amine(cas: 4316-58-9Quality Control of Tris(4-bromophenyl)amine) was used in this study.
In other references, Tris(4-bromophenyl)amine(cas: 4316-58-9) is often used in the synthesis of porous luminescent covalent–organic polymers (COPs)Quality Control of Tris(4-bromophenyl)amine
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary