In 2018,Hu, Xiao-Qiang; Hu, Zhiyong; Trita, A. Stefania; Zhang, Guodong; Goossen, Lukas J. published 《Carboxylate-directed C-H allylation with allyl alcohols or ethers》.Chemical Science published the findings.Quality Control of 3-Bromo-2-methylbenzoic acid The information in the text is summarized as follows:
A [Ru(p-cymene)Cl2]2 catalyst activated allyl alcs. and ethers for the regioselective ortho-C-H allylation of aromatic and heteroaromatic carboxylates. The reaction was orthogonal to most C-H functionalizations with allyl alcs. in that allyl arenes rather than carbonyl compounds were obtained. A wide range of substrates were thus smoothly transformed to allylarenes at 50 ° in phosphate-buffered 2,2,2-trichloroethanol. The reaction concept combined the use of abundant reagents and directing groups in a sustainable, waste-minimized method for C-C bond formation. The results came from multiple reactions, including the reaction of 3-Bromo-2-methylbenzoic acid(cas: 76006-33-2Quality Control of 3-Bromo-2-methylbenzoic acid)
3-Bromo-2-methylbenzoic acid(cas: 76006-33-2) belongs to organobromine compounds.Depending on the type of carbon to which the bromine is bonded, organic bromide could be alkyl, alkenyl, alkynyl, or aryl. Quality Control of 3-Bromo-2-methylbenzoic acid Dehydrobromination, Grignard reactions, reductive coupling, Wittig reaction, and several nucleophilic substitution reactions are some of the principal reactions which involve organic bromides.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary