Pardo-Rodriguez, Virtudes’s team published research in Chemical Communications (Cambridge, United Kingdom) in 48 | CAS: 69361-41-7

Chemical Communications (Cambridge, United Kingdom) published new progress about 69361-41-7. 69361-41-7 belongs to bromides-buliding-blocks, auxiliary class PROTAC Linker,Aliphatic Linker, name is (4-Bromobut-1-yn-1-yl)trimethylsilane, and the molecular formula is C7H13BrSi, HPLC of Formula: 69361-41-7.

Pardo-Rodriguez, Virtudes published the artcilePd-catalyzed borylative cyclisation of 1,7-enynes, HPLC of Formula: 69361-41-7, the publication is Chemical Communications (Cambridge, United Kingdom) (2012), 48(85), 10517-10519, database is CAplus and MEDLINE.

A variety of 1,7-enynes undergo nucleophilic boration and cyclization with bis(pinacolato)diboron catalyzed by Pd bis(trifluoroacetate), affording alkylidenecyclohexane-substituted homoallylic and allylic boronates by formation of C-C and C-B bonds. Reaction of CR3R4:CR2CH2XYCH2CCR1 [X = C(CO2Me)2, C(SO2Ph)2, Y = CH2; X = CH2, Y = C(CO2Me)2, NTs] with pin2B2, catalyzed by Pd(TFA)2 gave methylenecyclohexanes I (2a–i, 4a–h, R1 = H, Me, Ph, TMS; R2-R4 = H, Me, CH2OAc) together with cyclohexenylmethyl boronates II [5, Y = C(CO2Me)2, NTs]. The reaction mechanism comprises palladium addition to the triple bond with subsequent formation of palladaindene and elimination; the compounds 5 were rationalized as products of palladium-catalyzed isomerization of 4.

Chemical Communications (Cambridge, United Kingdom) published new progress about 69361-41-7. 69361-41-7 belongs to bromides-buliding-blocks, auxiliary class PROTAC Linker,Aliphatic Linker, name is (4-Bromobut-1-yn-1-yl)trimethylsilane, and the molecular formula is C7H13BrSi, HPLC of Formula: 69361-41-7.

Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary