Anand, Radhika published the artcileStereoselective Synthesis of Nonpsychotic Natural Cannabidiol and Its Unnatural/Terpenyl/Tail-Modified Analogues, Formula: C12H25Br, the publication is Journal of Organic Chemistry (2022), 87(7), 4489-4498, database is CAplus and MEDLINE.
Here, we report a three-step concise and stereoselective synthesis route to one of the most important phytocannabinoids, namely, (-)-cannabidiol (-CBD), from inexpensive and readily available starting material R-(+)-limonene. The synthesis involved the diastereoselective bifunctionalization of limonene, followed by effective elimination leading to the generation of key chiral p-mentha-2,8-dien-1-ol. The chiral p-mentha-2,8-dien-1-ol on coupling with olivetol under silver catalysis provided regiospecific (-)-CBD, contrary to reported ones which gave a mixture The newly developed approach was further extended to its structural analogs cannabidiorcin and other tail/terpenyl-modified analogs. Moreover, its opposite isomer (+)-cannabidiol was also successfully synthesized from S-(-)-limonene.
Journal of Organic Chemistry published new progress about 143-15-7. 143-15-7 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 1-Bromododecane, and the molecular formula is C12H25Br, Formula: C12H25Br.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary