Isobe, Hiroyuki published the artcileSynthesis of Fullerene Glycoconjugates via a Copper-Catalyzed Huisgen Cycloaddition Reaction, Recommanded Product: 7-Bromohept-1-yne, the publication is Organic Letters (2007), 9(22), 4611-4614, database is CAplus and MEDLINE.
The synthesis of fullerene-carbohydrate conjugates using a copper-catalyzed [3 + 2] cycloaddition reaction to facilitate the union of an azido- functionalized sugar and a pentaalkynyl[60]fullerene is reported. Fullerenes bearing five oligosaccharides such as globotriaosylceramide (Gb3)-trisaccharide can be readily accessed. Nanometer-scale mol. architectures presenting as many as 15 sugar moieties in C5-symmetry are readily produced. The cycloaddition reaction proceeds quant. under mild conditions without the need to protect the sugar hydroxyl groups.
Organic Letters published new progress about 81216-14-0. 81216-14-0 belongs to bromides-buliding-blocks, auxiliary class Linker,PROTAC Linker, name is 7-Bromohept-1-yne, and the molecular formula is C7H11Br, Recommanded Product: 7-Bromohept-1-yne.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary