Ruasse, Marie Francoise published the artcileSolvation and steric effects on electrophilic reactivity of ethylenic compounds. 1. Stereochemistry and bromination of congested adamantylidenealkanes, Category: bromides-buliding-blocks, the publication is Journal of Organic Chemistry (1990), 55(8), 2298-303, database is CAplus.
Rate constants for bromine addition to I (R, R1 given: H, H; H, Me; H, Et; H, Me2CH; H, Me3C; H, neopentyl; Me, Me; Et, Et; Me, Me2CH; Me2CH, Me2CH) were determined in MeOH and in AcOA. The data indicate that solvent effect is markedly smaller than that on linear alkenes, which suggests that greater steric retardation in I can be attributed to mechanistic changes: inhibition of nucleophilic solvent assistance in the ionization step and/or return resulting from a slow product-forming step.
Journal of Organic Chemistry published new progress about 594-81-0. 594-81-0 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 2,3-Dibromo-2,3-dimethylbutane, and the molecular formula is C6H12Br2, Category: bromides-buliding-blocks.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary