Mulders, J. published the artcileMechanism of dehalogenation of vic-dibromoalkanes by iodide ion. Duality of mechanisms for the process of direct elimination, HPLC of Formula: 594-81-0, the publication is Bulletin des Societes Chimiques Belges (1963), 322-45, database is CAplus.
cf. CA 58, 13737c. The iodide ion-induced elimination of Br from the following dibromides in Me2CO was studied spectrophotometrically by the method of initial rates: 1,2-dibromopropane, dl- and meso2,3-dibromobutanes, 1,2-dibromo-2-methylpropane, 2,3-dibromo-2-methylbutane, 2,3-dibromo-2,3-dimethylbutane, and meso-1,2-dibromo-1,2-diphenylethane. Values for k, E, and log PZ were calculated Reactions of the last 3 compounds had values of k greater than 10-5, were inhibited by salts not containing a common ion, and showed no effect (other than inhibition due to ionic forces) with LiBr; reactions of the other compounds had values of k less than 10-5, showed no effect with salts not containing a common ion, and were inhibited by LiBr. The results are interpreted in terms of the existence of an intermediate (I) for reactions of the 1st members of the series; reactions of the 3 last compounds probably involve a synchronous transition state (II).
Bulletin des Societes Chimiques Belges published new progress about 594-81-0. 594-81-0 belongs to bromides-buliding-blocks, auxiliary class Bromide,Aliphatic hydrocarbon chain, name is 2,3-Dibromo-2,3-dimethylbutane, and the molecular formula is C6H12Br2, HPLC of Formula: 594-81-0.
Referemce:
https://en.wikipedia.org/wiki/Bromide,
bromide – Wiktionary