Mild conversion of β-diketone and β-ketoesters to carboxylic acids was written by Zhang, Yang;Jiao, Jingliang;Flowers, Robert A. II. And the article was included in Journal of Organic Chemistry in 2006.Recommanded Product: 1-Bromo-6-methoxyhexane This article mentions the following:
A mild protocol for the conversion of β-ketoesters and β-diketone to carboxylic acids with use of CAN in CH3CN was described. The method was compatible with a number of functional groups, and could generate carboxylic acids under neutral conditions at room temperature The reaction was fast and general, providing an alternative method to the commonly used malonic ester acid preparation Initial mechanistic studies showed that initial oxidation of the enol form of the β-dicarbonyl initiated the reaction. The presence of nitrate as an oxidant ligand or as an additive was critical for success of the reaction. In the experiment, the researchers used many compounds, for example, 1-Bromo-6-methoxyhexane (cas: 50592-87-5Recommanded Product: 1-Bromo-6-methoxyhexane).
1-Bromo-6-methoxyhexane (cas: 50592-87-5) belongs to organobromine compounds. A variety of minor organobromine compounds are found in nature, but none are biosynthesized or required by mammals. Organobromine compounds have fallen under increased scrutiny for their environmental impact. Bromine-containing agents predominate because not only are they more efficient than similar chlorine-containing species, but also the high atomic weight of bromine ensures that it is present in a high mass fraction within most organobromine compounds.Recommanded Product: 1-Bromo-6-methoxyhexane
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary