Palladium-Catalyzed Enantioselective C(sp2)-H Imidoylation by Desymmetrization was written by Wang, Jian;Gao, De-Wei;Huang, Jinbo;Tang, Shi;Xiong, Zhuang;Hu, Huaanzi;You, Shu-Li;Zhu, Qiang. And the article was included in ACS Catalysis in 2017.Recommanded Product: 61150-57-0 This article mentions the following:
An efficient palladium-catalyzed enantioselective isocyanide insertion/desymmetrizing C(sp2)-H bond activation reaction allowed by a SPINOL-derived phosphoramidite ligand was developed. 3,4-Dihydroisoquinolines containing C3 quaternary stereogenic centers, e.g., I, were obtained in high yields with good enantioselectivity under mild conditions. In the experiment, the researchers used many compounds, for example, 2-Bromo-4-fluorobenzylbromide (cas: 61150-57-0Recommanded Product: 61150-57-0).
2-Bromo-4-fluorobenzylbromide (cas: 61150-57-0) belongs to organobromine compounds. Organo bromine compounds are versatile compounds and are widely used in diverse fields. Organo bromine derivatives are used in the dye sector, as an indicator in analytical chemistry (Bromothymol blue is a popular indicator). The reactivity of organobromine compounds resembles but is intermediate between the reactivity of organochlorine and organoiodine compounds. For many applications, organobromides represent a compromise of reactivity and cost.Recommanded Product: 61150-57-0
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary