Transition-Metal-Free Reverse Reactivity of (2-Alkynyl)-Arylaldimines: Assembly of Functionalized Amino-Indenones was written by Saini, Kapil Mohan;Saunthwal, Rakesh K.;Sushmita;Verma, Akhilesh K.. And the article was included in Chemistry – A European Journal in 2020.Related Products of 85118-24-7 This article mentions the following:
Transition-metal-free regioselective synthesis of functionalized amino-indenones by the reaction of ortho-alkynylaldehydes with a broad range of primary amines by intramol. cyclization was described. The designed reaction proceeded through KOH-mediated Prins-type cyclization and DMSO-promoted oxidation of the cyclopent-2-en-1-one system. The proposed mechanism and role of solvent were well supported by control experiments For the first time, the reverse reactivity of (2-alkynyl)-arylaldimines in a super basic system was reported. In the experiment, the researchers used many compounds, for example, 2-Bromo-4-(trifluoromethyl)benzaldehyde (cas: 85118-24-7Related Products of 85118-24-7).
2-Bromo-4-(trifluoromethyl)benzaldehyde (cas: 85118-24-7) belongs to organobromine compounds. Most organobromine compounds, like most organohalide compounds, are relatively nonpolar. Commercially available organobromine pharmaceuticals include the vasodilator nicergoline, the sedative brotizolam, the anticancer agent pipobroman, and the antiseptic merbromin. Related Products of 85118-24-7
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary