Mandal, Tanmoy et al. published their research in Journal of Organometallic Chemistry in 2021 | CAS: 35065-86-2

3-Bromophenyl acetate (cas: 35065-86-2) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. One prominent application of synthetic organobromine compounds is the use of polybrominated diphenyl ethers as fire-retardants, and in fact fire-retardant manufacture is currently the major industrial use of the element bromine.SDS of cas: 35065-86-2

Steric effect of NHC ligands in Pd(II)-NHC-catalyzed non-directed C-H acetoxylation of simple arenes was written by Mandal, Tanmoy;Yadav, Sudha;Choudhury, Joyanta. And the article was included in Journal of Organometallic Chemistry in 2021.SDS of cas: 35065-86-2 This article mentions the following:

Herein, a series of well-defined discrete [Pd(NHCRR1)(py)I2] complexes I [R = Me, Cy, n-Bu, Mes; R1 = Me, Cy, n-Bu, Mes, t-Bu, Ph; RR1 = Me, Cy, n-Bu, Mes] with systematically varied degree of spatial congestion at the Pd center, exerted through the R and R1 substituents on the NHC ligand, were explored in controlling the activity as well as the site-selectivity of non-directed acetoxylation of representative monosubstituted and disubstituted simple arenes (such as toluene, iodobenzene and bromobenzene, naphthalene and 1,2-dichlorobenzene). The resulting best yields were found to be 75% for toluene and 65% for bromobenzene with [Pd(NHCPhMe)(py)I2], 75% for iodobenzene and 79% for naphthalene with [Pd(NHCMeMe)(py)I2], and 41% for 1,2-dichlorobenzene with [Pd(NHCCyCy)(py)I2]. Most importantly, with increasing the bulkiness of the NHC ligand in the complexes, the selectivity of the distal C-acetoxylated products in comparison to the proximal ones, was enhanced to a great extent in all cases. Considering the vast library of NHC ligands, this study underscores the future opportunity to develop more strategies to improve the activity and the crucial site-selectivity of C-H functionalization reactions in simple as well as complex organic mols. In the experiment, the researchers used many compounds, for example, 3-Bromophenyl acetate (cas: 35065-86-2SDS of cas: 35065-86-2).

3-Bromophenyl acetate (cas: 35065-86-2) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. One prominent application of synthetic organobromine compounds is the use of polybrominated diphenyl ethers as fire-retardants, and in fact fire-retardant manufacture is currently the major industrial use of the element bromine.SDS of cas: 35065-86-2

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary