Bothe, Harald et al. published their research in Chemische Berichte in 1991 | CAS: 4457-67-4

1-Bromo-4-methoxybutane (cas: 4457-67-4) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. alpha-Bromoesters are employed in the Reformatsky reaction for the synthesis of beta-hydroxyesters. Bromine-containing agents predominate because not only are they more efficient than similar chlorine-containing species, but also the high atomic weight of bromine ensures that it is present in a high mass fraction within most organobromine compounds.Related Products of 4457-67-4

Synthesis of monosubstituted [1.1.1]propellanes was written by Bothe, Harald;Schlueter, Arnulf Dieter. And the article was included in Chemische Berichte in 1991.Related Products of 4457-67-4 This article mentions the following:

Wittig reaction of (ClCH2)2CO with RCH:PPh3 [R = Me(CH2)n, MeO(CH2)m; n = 4, 6, 10; m = 3, 5] in Et2O-hexane gave 32-48% RCH:C(CH2Cl)2, which underwent cycloaddition with :CBr2 to give 20-57% bis(chloromethyl)dibromocyclopropanes I. Treating I with MeLi in Et2O gave 21-64% title propellanes II, which polymerized spontaneously at room temperature in the absence of inhibitors. In the experiment, the researchers used many compounds, for example, 1-Bromo-4-methoxybutane (cas: 4457-67-4Related Products of 4457-67-4).

1-Bromo-4-methoxybutane (cas: 4457-67-4) belongs to organobromine compounds. Bromo compounds are employed in a variety of metal-catalyzed coupling reactions. They are also ideal candidates for the synthesis of Grignard reagents that have wide-applicability in organic synthesis. alpha-Bromoesters are employed in the Reformatsky reaction for the synthesis of beta-hydroxyesters. Bromine-containing agents predominate because not only are they more efficient than similar chlorine-containing species, but also the high atomic weight of bromine ensures that it is present in a high mass fraction within most organobromine compounds.Related Products of 4457-67-4

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary