Electric Literature of 108-85-0, Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. 108-85-0, Name is Bromocyclohexane, SMILES is BrC1CCCCC1, belongs to bromides-buliding-blocks compound. In a article, author is Hussein, Mohanad A., introduce new discover of the category.
Halide Anion Triggered Reactions of Michael Acceptors with Tropylium Ion
Tropylium bromide undergoes noncatalyzed, regioselective additions to a large variety of Michael acceptors. In this way, acrylic esters are converted into beta-bromo-alpha-cycloheptatrienylpropionic esters. The reactions are interpreted as nucleophilic attack of bromide ions at the electron-deficient olefins and the approach of the tropylium ion to the incipient carbanion. Quantum chemical calculations were performed to elucidate the analogy to the amine- or phosphine-catalyzed Rauhut-Currier reactions. Subsequent synthetic transformations of the bromo-cycloheptatrienylated adducts are reported.
Electric Literature of 108-85-0, Because enzymes can increase reaction rates by enormous factors and tend to be very specific, typically producing only a single product in quantitative yield, they are the focus of active research.you can also check out more blogs about 108-85-0.