Catalysts are substances that increase the reaction rate of a chemical reaction without being consumed in the process. 539-74-2, Name is Ethyl 3-bromopropanoate, SMILES is CCOC(=O)CCBr, belongs to bromides-buliding-blocks compound. In a document, author is Guo, Jingyu, introduce the new discover, Category: bromides-buliding-blocks.
Sn2B5O9Br as an Outstanding Bifunctional Material with Strong Second-Harmonic Generation Effect and Large Birefringence
The first tin (II) borate bromide, Sn2B5O9Br (SBOB), as an outstanding bifunctional material with excellent linear and nonlinear optical (NLO) performance is synthesized successfully. As far as it is known, it exhibits the largest birefringence among the reported borates (0.439 at 546 nm), even over famous birefringent materials YVO4 and TiO2. Meanwhile, it also owns a strong second harmonic generation (SHG) response of 2.4 times that of KH2PO4. Theoretical calculations display that its incredible optical properties mainly originate from the extremely intensive stereochemical activity lone pair (SCALP) of [SnO7Br2] polyhedra, which results in the enhancement of birefringence and SHG response, increasing to 2.6- and 4.8-fold, respectively, from Sn2B5O9Cl (SBOC) to SBOB. These perceptions will guide and accelerate the exploration of excellent birefringence and NLO materials in tin (II)-based compound.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 539-74-2 is helpful to your research. Category: bromides-buliding-blocks.