Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 766-96-1, Name is 1-Bromo-4-ethynylbenzene, molecular formula is C8H5Br, belongs to bromides-buliding-blocks compound. In a document, author is Sahlabji, Taher, introduce the new discover, Application In Synthesis of 1-Bromo-4-ethynylbenzene.
Spontaneous epoxidation of styrene catalyzed by flower-like NiO nanoparticles under ambient conditions
Flower-like NiO microspheres with an average size of 3 mu mand nanoflakes size 10-100 nm were synthesized by surfactant-assisted chemical precipitation method, using Ni(CH3CO2)(2)center dot 4H(2)O as a nickel source, diethanolamine as a complexing agent, and cetyltrimethylammonium bromide as a surfactant. The obtain material was characterized by SEM, EDX, HRTEM, XRD, and TGA. The obtained results confirmed the formation of highly ordered flower-like NiO nanoparticles. The catalytic activity of the obtained material was evaluated in the epoxidation reaction of styrene u n d e r a m b i e n t c o n d i t i o n s, us ing m e t a chloroperoxybenzoic acid (m-CPBA) as an oxidant. The obtained results revealed an immediate conversion of styrene to styrene oxide, with high conversion (87%), medium selectivity (65%), and high turnover-frequency (TOF) (243 s(-1)). However, when bulk NiO was applied only 62% conversion with 68% selectivity and TOF = 174 s(-1) were obtained. Furthermore, this catalyst is was easily separable and recyclable. Moreover, a possible reaction mechanism is also proposed.
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