Rao, Changqing; Mai, Shaoyu; Song, Qiuling published the artcile< Rh(II)/phosphine-cocatalyzed synthesis of dithioketal derivatives from diazo compounds through simultaneous construction of two different C-S bonds>, Application In Synthesis of 14062-30-7, the main research area is dithioketal preparation rhodium phosphine catalyst diazo carbon sulfur bond.
Rhodium(II)/phosphine-cocatalyzed bis-sulfuration of α-diazocarbonyl compounds using thiosulfonates as the sulfenylating agent, which provided two sulfur-containing moieties, was developed via simultaneous inter- and intra-mol. C-S bond formation. This novel protocol provides a rapid synthetic route to dithioketal derivatives in moderate to good yields in an atom-economic process. The transformation is proposed to proceed through phosphine ylide formation followed by S(O2)-S bond cleavage and rearrangement.
Chemical Communications (Cambridge, United Kingdom) published new progress about C-S bond formation. 14062-30-7 belongs to class bromides-buliding-blocks, and the molecular formula is C10H11BrO2, Application In Synthesis of 14062-30-7.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary