Singh, Puspendra; Singh, Priyanka; Shabbani, Gulam; Butcher, Ray J. published the artcile< Synthesis and single crystal X-ray studies of dimesityl ditelluride: [2,4,6-Me3C6H2Te]2>, Product Details of C9H11Br, the main research area is mesityl ditelluride preparation crystal structure supramol synthon.
The reaction of freshly prepared mesityl magnesium bromide with tellurium powder in anhydrous THF provided the dimesityl ditelluride: [2,4,6-Me3C6H2Te]2. A suitable needle- shaped crystal of dimesityl ditelluride was developed by evaporation of a solution in chloroform. The Te compound was developed with the orthorhombic space group Iba2 with a = 15.2916(7) Å, b = 15.7225(7) Å, c = 14.5272(7) Å and α, β,γ = 90°. The geometry about the central tellurium atoms adopt a bent-shaped geometry with torsion angle C10-Te2-Te1- C1 = 87.0(3)° and this may be considered a cisoid conformation. Intermol. C-H…·Te interactions give rise to a two-dimensional supramol. synthons in its crystalline state. The crystal packing diagram shows Te….H [Te1…·H5A, 3.2557(5) Å & Te1…·H8C, 3.2578(5) Å] hydrogen-bonding interactions which are responsible for associative forces.
Journal of Physics: Conference Series published new progress about Bond angle, torsional. 576-83-0 belongs to class bromides-buliding-blocks, and the molecular formula is C9H11Br, Product Details of C9H11Br.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary