Wang, Meng; Chen, Jun; Chen, Zongjia; Zhong, Changxu; Lu, Ping published the artcile< Enantioselective Desymmetrization of Cyclobutanones Enabled by Synergistic Palladium/Enamine Catalysis>, Computed Properties of 135999-16-5, the main research area is cyclobutanone enantioselective desymmetrization palladium enamine catalyst; arylation; cyclobutanones; desymmetrization; palladium; synergistic catalysis.
The enantioselective intramol. α-arylation of cyclobutanones was established by combining palladium and enamine catalyst systems. Two different enantioselective control strategies were developed for cyclobutanone substrates bearing O- or N-tethered aryl bromides. Further synthetic applications are also reported.
Angewandte Chemie, International Edition published new progress about Arylation. 135999-16-5 belongs to class bromides-buliding-blocks, and the molecular formula is C7H7BrO2, Computed Properties of 135999-16-5.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary