Li, Yun-Fei; Zhang, Duo; Wang, Hui-Juan; Li, Fa-Bao; Sun, Liang; Liu, Li; Liu, Chao-Yang; Asiri, Abdullah M.; Alamry, Khalid A. published the artcile< Metal-Free Synthesis of N-Alkyl-2,5-Unsubstituted/Monosubstituted Fulleropyrrolidines: Reaction of [60]Fullerene with Paraformaldehyde and Amines>, Related Products of 3959-07-7, the main research area is alkyl fulleropyrrolidine thermal synthesis fullerene paraformaldehyde amines.
A series of scarce N-alkyl-2,5-unsubstituted/monosubstituted fulleropyrrolidines were synthesized in moderate to excellent yields by the simple one-step thermal reaction of [60]fullerene with primary/secondary amines in the presence of paraformaldehyde without the addition of valuable metal salts. Intriguingly, the reaction with primary amines unexpectedly afforded N-alkyl-2,5-unsubstituted fulleropyrrolidines instead of the anticipated 2,5-monosubstituted fulleropyrrolidines. A plausible reaction pathway is proposed to elucidate the above-mentioned reaction process based on the exptl. results.
Journal of Organic Chemistry published new progress about Fullerenes Role: SPN (Synthetic Preparation), PREP (Preparation) (pyrrolidines). 3959-07-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H8BrN, Related Products of 3959-07-7.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary