Gong, Zehao; Wang, Yixin; Yan, Qiang published the artcile< Polymeric partners breathe together: using gas to direct polymer self-assembly via gas-bridging chemistry>, Name: 2,4,6-Trimethylbromobenzene, the main research area is self assembly gas bridging chem polymer breathe.
The quest for a general and facile way to regulate polymer self-assembled nanostructures with low- to high-order ergodicity is an eternal theme in soft nanoparticle fabrication. Here we present an unprecedented gas-bridging strategy that allows to use gas to direct polymer self-assembly in continuous and tunable manners. Such system comprises a partner of frustrated Lewis polymers with bulky Lewis acid and base groups. They can together ′breathe in′ external gases to form gas-bridged structures between the two complementary moieties, which drive their mutual complexation and assemble into polymer nanoparticles of diverse geometries and dimensionalities. This strategy is applicable to a broad family of gas substances including but not limited to carbon oxides, nitrogen oxides, sulfur oxides, and even olefins; moreover, tailoring gas types and levels can dictate distinct assembling evolutionary pathways and deformable behaviors among spherical, fibrous, polymersomal, tubesomal and cubosomal morphologies. We also discover that the gas-based bonding chem. is the mechanistic basis underlying the phase transitional control and phase window regulation. This will open a new direction of making bespoke polymer nanostructures with gas.
Science China: Chemistry published new progress about Alkenes Role: PEP (Physical, Engineering or Chemical Process), PROC (Process). 576-83-0 belongs to class bromides-buliding-blocks, and the molecular formula is C9H11Br, Name: 2,4,6-Trimethylbromobenzene.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary