Lahtigui, Ouidad; Forster, Dan; Duchemin, Coralie; Cramer, Nicolai published the artcile< Enantioselective Access to 3-Azabicyclo[3.1.0]hexanes by CpxRhIII Catalyzed C-H Activation and Cp*IrIII Transfer Hydrogenation>, Reference of 3959-07-7, the main research area is azabicyclohexane enantioselective diastereoselective preparation; cyclopropane enantioselective diastereoselective preparation amine CH activation transfer hydrogenation; enoxysuccinimide alkenyl aldehyde enantioselective diastereoselective cyclopropanation.
A flexible two-step protocol for efficient and selective access such as 3-azabicyclo[3.1.0]hexanes I [R1 = cyclopropyl, Ph, 3-thienyl, etc.; R2 = Bn, PNB] was disclosed. A tailored CpxRhIII catalyst promoted alkenyl C-H functionalization of N-enoxysuccinimides engaging in rare cis-cyclopropanation of acrolein to access disubstituted cis-cyclopropanes in high enantio- and diastereoselectivity. Subsequently, in the presence of a broad range of primary amines, the dicarbonyl cis-cyclopropanes were efficiently and completely diastereoselectively cyclized by a Cp*IrIII catalyst via an iterative aminative transfer hydrogen to an exquisite set of substituted 3-azabicyclo[3.1.0]hexanes.
ACS Catalysis published new progress about C-H bond activation. 3959-07-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H8BrN, Reference of 3959-07-7.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary