Yuan, Ziliang; Liu, Bing; Zhou, Peng; Zhang, Zehui; Chi, Quan published the artcile< Preparation of nitrogen-doped carbon supported cobalt catalysts and its application in the reductive amination>, Recommanded Product: 4-Bromobenzylamine, the main research area is amine preparation green chem; aldehyde reductive amination cobalt nanocatalyst.
The use of non-noble metal catalysts with high activity is of great importance for organic transformations. Herein, nitrogen-doped carbon supported cobalt catalysts with high surface area up to 981.2 m2/g were prepared via the simple pyrolysis of cobalt coordinated organic polymers with silica as the hard template. The pyrolysis temperature showed a great effect on the structure and properties of the as-prepared catalysts. The Co@NC-800 catalyst with the pyrolysis temperature of 800 °C demonstrated a high activity for the selective reductive amination of carbonyl compounds RCHO (R = CH3(CH2)6, furan-2-yl, cyclohexyl, etc.) to primary amines RCH2NH2 with ammonia and hydrogen. Structurally-diverse primary amines with yields in the range from 81.8% to 100% were attained under the optimal conditions. The Co@NC-800 catalyst could be reused without the loss of its activity. The Co@NC-800 catalyst demonstrated comparable activity as the reported heterogeneous noble metal catalysts.
Journal of Catalysis published new progress about Aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 3959-07-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H8BrN, Recommanded Product: 4-Bromobenzylamine.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary