Jimenez-Almarza, Alicia; Lopez-Magano, Alberto; Mas-Balleste, Ruben; Aleman, Jose published the artcile< Tuning the Activity-Stability Balance of Photocatalytic Organic Materials for Oxidative Coupling Reactions>, Quality Control of 3959-07-7, the main research area is imine preparation; amine oxidative coupling photocatalytic; amines; imines; organic materials; oxidative coupling; photocatalysis.
In the series of materials reported herein, the triazine-based material shows the optimal compromise between activity and stability when studied for the oxidative coupling of amines, achieving imine products. Accordingly, while significant leaching of mol. active fragments was ruled out for triazine-based polymers, other materials of the series show a significant chem. erosion as a result of the reaction with the amine substrates. Consequently, only a triazine-based material allowed performing several catalytic cycles (up to seven) with yields higher than 80%. The applicability of this heterogeneous catalyst had been proven with a variety of substrates, confirming its stability and obtaining diverse imine coupling products with excellent yields.
ACS Applied Materials & Interfaces published new progress about Amines Role: RCT (Reactant), RACT (Reactant or Reagent). 3959-07-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H8BrN, Quality Control of 3959-07-7.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary