Li, Huiqiong; Feng, Huangdi; Wang, Fang; Huang, Liliang published the artcile< Carboxyl Transfer of α-Keto Acids toward Oxazolidinones via Decarboxylation/Fixation of Liberated CO2>, Safety of 4-Bromobenzylamine, the main research area is copper catalyst carboxyl transfer alpha keto acid decarboxylation fixation; liberated carbon dioxide decarboxylation; oxazolidinone preparation.
A novel strategy for the direct carboxyl transfer involving a decarboxylative A3 reaction of α-keto acids, primary amines, and alkynes has been developed under a Cu(I)/Cu(II) binary catalysis system. This multicomponent reaction provides a facile and efficient approach for the production of a diverse range of 2-oxazolidinones in moderate to excellent yields through a one-pot CO2 elimination-fixation procedure. The conciseness of the “”CO2 recycling”” process makes this ideal synthesis superior over classical CO2 utilization.
Journal of Organic Chemistry published new progress about Alkynes, α- Role: RCT (Reactant), RACT (Reactant or Reagent). 3959-07-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H8BrN, Safety of 4-Bromobenzylamine.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary