Product Details of 13465-09-3In 2018 ,《Indium(III) as π-acid catalyst for the electrophilic activation of carbon-carbon unsaturated systems》 appeared in Organic & Biomolecular Chemistry. The author of the article were Perez Sestelo, Jose; Sarandeses, Luis A.; Martinez, M. Montserrat; Alonso-Maranon, Lorena. The article conveys some information:
A review. This review focuses on the utilization of indium(III) as a π-acid for the activation of C-C unsaturated bonds in organic synthesis. In addition to its well-known σ-coordination with carbonyl derivatives, indium(III) undergoes efficient π-coordination with unsaturated systems to trigger nucleophilic addition Accordingly, indium(III) halides and salts (InX3, X = Cl, Br, I, OTf, ONf, NTf2) have been reported as useful catalysts for a broad range of carbon-carbon and carbon-heteroatom bond formation reactions, including hydrofunctionalization (hydroarylation, hydroamination, hydroalkoxylation, and hydrothiolation), enyne cycloisomerization, and related reactions. In these reactions the counterion has a significant effect on the catalytic activity, and the development of novel In(III) complexes and the generation of highly electrophilic cationic indium(III) species has increased its synthetic applications as a π-acid catalyst. The experimental process involved the reaction of Indium(III) bromide(cas: 13465-09-3Product Details of 13465-09-3)
Indium(III) bromide(cas: 13465-09-3) is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells.Product Details of 13465-09-3
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary