Ung, Sosthene P.-M.; Perepichka, Inna; Li, Chao-Jun published the artcile< Visible-Light Mediated Photooxidative Phosphorylation of Benzylamines: A Novel and Mild Pathway Towards α-Aminophosphorus Compounds>, COA of Formula: C7H8BrN, the main research area is benzylamine oxidative photochem phosphinylation preparation aminophosphine oxide; benzylidene benzylamine photochem generation addition preparation secondary aminophosphine oxide; iridium phenylpyridine bipyridine photocatalyst benzylamine oxidative preparation aminophosphine oxide.
Traditional syntheses of α-aminophosphorus therapeutic targets proceed through the hydrophosphorylation of C:N or C:O bonds, thus necessitating preliminary oxidized substrates. Cross-dehydrogenative coupling strategies can bypass this extra oxidation step by oxidizing simpler substrates in situ before phosphorylating them, but those protocols can suffer from the use of toxic stoichiometric oxidants. Photochem. strategies can access those oxidized intermediates without any harsh conditions and can use mol. oxygen as a benign and sustainable oxidant. We report herein a simple protocol using visible light, phosphinylidenes and benzylamine derivatives for the synthesis of α-aminophosphorus products under aerobic conditions and using an iridium photosensitizer.
Helvetica Chimica Acta published new progress about Aralkyl amines Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation) (benzylamines). 3959-07-7 belongs to class bromides-buliding-blocks, and the molecular formula is C7H8BrN, COA of Formula: C7H8BrN.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary