Organobromine compounds, also called organobromides, are organic compounds that contain carbon bonded to bromine. 20469-65-2, formula is C8H9BrO2, The most pervasive is the naturally produced bromomethane. Application In Synthesis of 20469-65-2
Miller-Clark, Lyndsy A.;Christ, Peter E.;Ren, Tong research published 《 Diruthenium aryl compounds – tuning of electrochemical responses and solubility》, the research content is summarized as follows. Reported herein are the two new series of diruthenium aryl compounds I, [Ru(μ-DiMeOap)4RuAr] [DiMeOap = 2-(3,5-dimethoxyanilino)pyridinate; 1a–6a, X = 3,5-(MeO)2; Ar = 4-Me2C6H4, tBuC6H4, 4-MeOC6H4, 3,5-(MeO)2C6H3, 4-F3CC6H4, Ph] and [Ru2(m-iPrOap)4(Ar)] [1b–5b; m-iPrOap = 2-(3-iso-propoxyanilino)pyridinate; X = 3-iPrO], prepared through the lithium-halogen exchange reaction with a variety of aryl halides ArX. The mol. structures of these compounds were established with X-ray diffraction studies. Addnl., these compounds were characterized using electronic absorption and voltammetric techniques. Compounds 1a–6a and 1b–5b are all in the Ru25+ oxidation state, with a ground state configuration of σ2π4δ2(π*δ*)3 (S = 3/2). Use of the modified ap ligands resulted in moderate increases of product yield when compared to the unsubstituted Ru2(ap)4(Ar) (ap = 2-anilinopyridinate) series. Comparisons of the electrochem. properties of 1a–6a and 1b–5b against the Ru2(ap’)Cl starting material reveals the addition of the aryl ligand cathodically shifted the Ru26+/5+ oxidation and Ru25+/4+ reduction potentials. These oxidation and reductions potentials are also strongly dependent on the p-substituent of the axial aryl ligands.
Application In Synthesis of 20469-65-2, 1-Bromo-3,5-dimethoxybenzene, also known as 1-Bromo-3,5-dimethoxybenzene, is a useful research compound. Its molecular formula is C8H9BrO2 and its molecular weight is 217.06 g/mol. The purity is usually 95%.
1-Bromo-3,5-dimethoxybenzene is used as an intermediate in the synthetic preparation of pharmaceutical inhibitors via cross-coupling reactions.
1-Bromo-3,5-dimethoxybenzene can be synthesized by using 1,3-dimethoxybenzene via iridium-catalyzed arene borylation.
1-Bromo-3,5-dimethoxybenzene (1BDMB) is a synthetic molecule that can be used as an electron acceptor in organic photovoltaic cells. 1BDMB is a salt of the sodium salt of resorcylic acid and 1,3-dibromo-5,5-dimethoxybenzene. It has been shown to have a radical mechanism for the generation of free radicals. The radical mechanism is initiated by light absorption by the ruthenium complex at the center of the molecule which induces photoinduced electron transfer from the ruthenium to 1BDMB. This process results in electron transfer from the donor to an acceptor molecule, such as oxygen or nitrogen. The pharmacokinetic properties of this compound are not well known; however, it has been demonstrated that it can be synthesized through a cross-coupling reaction with other aromatic compounds such as stemofuran., 20469-65-2.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary