Organic compounds having carbon bonded to bromine are called organic bromides. 20469-65-2, formula is C8H9BrO2, Name is 1-Bromo-3,5-dimethoxybenzene. Depending on the type of carbon to which the bromine is bonded, organic bromide could be alkyl, alkenyl, alkynyl, or aryl. Quality Control of 20469-65-2.
Shao, Li-Dong;Chen, Yang;Wang, Mei;Xiao, Nan;Zhang, Zhi-Jun;Li, Dashan;Li, Rong-Tao research published 《 Palladium-catalyzed direct γ-C(sp3)-H arylation of β-alkoxy cyclohexenones: reaction scope and mechanistic insights》, the research content is summarized as follows. A mild Pd-catalyzed method for direct γ-C(sp3)-arylation of various unactivated β-alkoxy cyclohexenones was reported. The method is not only tolerated well with many ortho-hetero substituted aryl bromides but also with the sterically hindered ortho-dimethoxy or rigid ortho-diaryl aryl bromides. Mechanistic studies suggested the tunneling was likely to govern the [1,5]-H shift of the α’-dienolate-PdArL intermediate and consequently forms the γ-arylated product, therefore exhibiting an excellent γ-site selectivity. Finally, this method enabled the facile synthesis of CBD-like compounds with selective anti-proliferative effects against glioma stem cells.
20469-65-2, 1-Bromo-3,5-dimethoxybenzene, also known as 1-Bromo-3,5-dimethoxybenzene, is a useful research compound. Its molecular formula is C8H9BrO2 and its molecular weight is 217.06 g/mol. The purity is usually 95%.
1-Bromo-3,5-dimethoxybenzene is used as an intermediate in the synthetic preparation of pharmaceutical inhibitors via cross-coupling reactions.
1-Bromo-3,5-dimethoxybenzene can be synthesized by using 1,3-dimethoxybenzene via iridium-catalyzed arene borylation.
1-Bromo-3,5-dimethoxybenzene (1BDMB) is a synthetic molecule that can be used as an electron acceptor in organic photovoltaic cells. 1BDMB is a salt of the sodium salt of resorcylic acid and 1,3-dibromo-5,5-dimethoxybenzene. It has been shown to have a radical mechanism for the generation of free radicals. The radical mechanism is initiated by light absorption by the ruthenium complex at the center of the molecule which induces photoinduced electron transfer from the ruthenium to 1BDMB. This process results in electron transfer from the donor to an acceptor molecule, such as oxygen or nitrogen. The pharmacokinetic properties of this compound are not well known; however, it has been demonstrated that it can be synthesized through a cross-coupling reaction with other aromatic compounds such as stemofuran., Quality Control of 20469-65-2
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary