Grollier, Kevin; Taponard, Alexis; De Zordo-Banliat, Arnaud; Magnier, Emmanuel; Billard, Thierry published an article in 2020, the title of the article was Metal-free nucleophilic trifluoromethylselenolation via an iodide-mediated umpolung reactivity of trifluoromethylselenotoluenesulfonate.Related Products of 2567-29-5 And the article contains the following content:
Herein, a practical method to generate CF3Se- (and RFSe-) anions from shelf-stable reagents under iodide activation was reported. Metal-free nucleophilic trifluoromethylselenolations have been then performed with this in situ-generated anion. Perfluoroalkylselenolations have also been described. The umpolung reactivity of trifluoromethylselenotoluenesulfonates 4-CH3C6H4S(O)2SeR (R = trifluoromethyl, 1,1,2,2,2-pentafluoroethyl, 1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexyl) can be performed under reductive or oxidative conditions with alkyl halides R1X (R1 = dodecyl, Bn, (5-nitrofuran-2-yl)methyl, etc.; X = Br, Cl) to give desired products R1SeR. The experimental process involved the reaction of 4-(Bromomethyl)-1,1′-biphenyl(cas: 2567-29-5).Related Products of 2567-29-5
The Article related to selenide preparation, trifluoromethyl selenotoluenesulfonate alkyl halide perfluoroalkylselenolation, fluorine, nucleophilic substitution, perfluoroalkylselenolation, selenium, trifluoromethylselenolation and other aspects.Related Products of 2567-29-5
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary