Category: 13465-09-3

Schafer, Thomas C.; Becker, Jonathan; Seuffert, Marcel T.; Heuler, Dominik; Sedykh, Alexander E.; Mueller-Buschbaum, Klaus published an article in 2022. The article was titled 《Iodine-Chemisorption, Interpenetration and Polycatenation: Cationic MOFs and CPs from Group 13 Metal Halides and Di-Pyridyl-Linkers》, and you may find the article in Chemistry – A European Journal.Category: bromides-buliding-blocks The information in the text is summarized as follows:

Eight cationic, two-dimensional metal-organic frameworks (MOFs) were synthesized in reactions of the group 13 metal halides AlBr3, AlI3, GaBr3, InBr3 and InI3 with the dipyridyl ligands 1,2-di(4-pyridyl)ethylene (bpe), 1,2-di(4-pyridyl)ethane (bpa) and 4,4′-bipyridine (bipy). Seven of them follow the general formula 2∞[MX2(L)2]A, M = Al, In, X = Br, I, A-=[MX4]-, I-, I3-, L = bipy, bpa, bpe. Thereby, the porosity of the cationic frameworks can be used to take up the heavy mol. iodine in gas-phase chemisorption vital for the capture of iodine radioisotopes. This is achieved by switching between I- and the polyiodide I3- in the cavities at room temperature, including single-crystal-to-single-crystal transformation. The MOFs are 2-dimensional networks that exhibit (4,4)-topol. in general or (6,3)-topol. for 2∞[(GaBr2)2(bpa)5][GaBr4]2·bpa. The two-dimensional networks can either be arranged to an inclined interpenetration of the cationic two-dimensional networks, or to stacked networks without interpenetration. Interpenetration is accompanied by polycatenation. Due to the cationic character, the MOFs require the counterions [MX4]-, I- or I3- counterions in their pores. Whereas the [MX4]-, ions are immobile, iodide allows for chemisorption. Also, eight addnl. coordination polymers and complexes were identified and isolated that elaborate the reaction space of the herein reported syntheses. In the part of experimental materials, we found many familiar compounds, such as Indium(III) bromide(cas: 13465-09-3Category: bromides-buliding-blocks)

Indium(III) bromide(cas: 13465-09-3) is used in organic synthesis as a water tolerant Lewis acid. It efficiently catalyzes the three-component coupling of β-keto esters, aldehydes and urea (or thiourea) to afford the corresponding dihydropyrimidinones.Category: bromides-buliding-blocks

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

HPLC of Formula: 13465-09-3In 2021 ,《High-Rate Long Cycle-Life Li-Air Battery Aided by Bifunctional InX3 (X = I and Br) Redox Mediators》 appeared in ACS Applied Materials & Interfaces. The author of the article were Rastegar, Sina; Hemmat, Zahra; Zhang, Chengji; Plunkett, Samuel; Wen, Jianguo; Dandu, Naveen; Rojas, Tomas; Majidi, Leily; Misal, Saurabh N.; Ngo, Anh T.; Curtiss, Larry A.; Salehi-Khojin, Amin. The article conveys some information:

Redox mediators (RMs) are solution-based additives that have been extensively used to reduce the charge potential and increase the energy efficiency of Li-oxygen (Li-O2) batteries. However, in the presence of RMs, achieving a long cycle-life operation of Li-O2 batteries at a high current rate is still a major challenge. In this study, we discover a novel synergy among InX3 (X = I and Br) bifunctional RMs, molybdenum disulfide (MoS2) nanoflakes as the air electrode, DMSO/ionic liquid hybrid electrolyte, and LiTFSI as a salt to achieve long cycle-life operations of Li-O2 batteries in a dry air environment at high charge-discharge rates. Our results indicate that batteries with InI3 operate up to 450 cycles with a c.d. of 0.5 A g-1 and 217 cycles with a c.d. of 1 A g-1 at a fixed capacity of 1 A h g-1. Batteries with InBr3 operate up to 600 cycles with a c.d. of 1 A g-1. These batteries can also operate at a higher charge rate of 2 A g-1 up to 200 cycles (for InBr3) and 160 cycles (for InI3). Our exptl. and computational results reveal that while X3- is the source of the redox mediator, LiX at the MoS2 cathode, In3+ reacts on the lithium anode side to form a protective layer on the surface, thus acting as an effective bifunctional RM in a dry air environment. This evidence for a simultaneous improvement in the current rates and cycle life of a battery in a dry air atm. opens a new direction for research for advanced energy storage systems. The results came from multiple reactions, including the reaction of Indium(III) bromide(cas: 13465-09-3HPLC of Formula: 13465-09-3)

Indium(III) bromide(cas: 13465-09-3) is used in organic synthesis as a water tolerant Lewis acid. It efficiently catalyzes the three-component coupling of β-keto esters, aldehydes and urea (or thiourea) to afford the corresponding dihydropyrimidinones.HPLC of Formula: 13465-09-3

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

In 2018,Alonso-Maranon, Lorena; Sarandeses, Luis A.; Martinez, M. Montserrat; Perez Sestelo, Jose published 《Synthesis of fused chromenes by the indium(III)-catalyzed cascade hydroarylation/cycloisomerization reactions of polyyne-type aryl propargyl ethers》.Organic Chemistry Frontiers published the findings.Product Details of 13465-09-3 The information in the text is summarized as follows:

Fused 2H-chromenes were prepared by the cascade hydroarylation/cycloisomerization reactions of polyyne-type aryl propargyl ethers using indium(III) catalysis. The transformation proceeded with 6-endo-dig regioselectivity using InBr3 (5 mol%). The method was extended to triynes allowing the formation of three bonds in one pot. Indium(III) also catalyzed the hydroamination/hydroarylation cascade reaction of o-aryldiynyl anilines to form fused carbazoles. In the experimental materials used by the author, we found Indium(III) bromide(cas: 13465-09-3Product Details of 13465-09-3)

Indium(III) bromide(cas: 13465-09-3) is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells.Product Details of 13465-09-3

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Baalbaki, Hassan A.; Roshandel, Hootan; Hein, Jason E.; Mehrkhodavandi, Parisa published their research in Catalysis Science & Technology in 2021. The article was titled 《Conversion of dilute CO2 to cyclic carbonates at sub-atmospheric pressures by a simple indium catalyst》.Related Products of 13465-09-3 The article contains the following contents:

The transformation of CO2 to value added commodity chems. presents an impactful strategy to obtain products that are less dependent on fossil fuels. In this study, indium tribromide (InBr3) mixed with tetrabutylammonium bromide (NBu4Br) co-catalyst has been identified as a simple, highly efficient catalyst for the synthesis of cyclic carbonates from epoxides and CO2 at sub-atm. pressures, room temperature, and under solvent-free conditions. The InBr3/NBu4Br catalytic system is tolerant toward different functional groups with high conversions and >99% selectivity for cyclic carbonate without resorting to high pressures and temperatures Moreover, a combination of in situ IR, NMR spectroscopy, and substrate labeling experiments enabled the proof of key catalytic steps and detection of reaction intermediates to elucidate the reaction mechanism. This technol. represents a potential scalable system for the utilization of waste CO2. After reading the article, we found that the author used Indium(III) bromide(cas: 13465-09-3Related Products of 13465-09-3)

Indium(III) bromide(cas: 13465-09-3) is used in organic synthesis as a water tolerant Lewis acid. It efficiently catalyzes the three-component coupling of β-keto esters, aldehydes and urea (or thiourea) to afford the corresponding dihydropyrimidinones.Related Products of 13465-09-3

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

In 2018,Advanced Materials (Weinheim, Germany) included an article by Song, Jizhong; Fang, Tao; Li, Jianhai; Xu, Leimeng; Zhang, Fengjuan; Han, Boning; Shan, Qingsong; Zeng, Haibo. Recommanded Product: Indium(III) bromide. The article was titled 《Organic-Inorganic Hybrid Passivation Enables Perovskite QLEDs with an EQE of 16.48%》. The information in the text is summarized as follows:

Perovskite quantum dots (QDs) with high photoluminescence quantum yields (PLQYs) and narrow emission peak hold promise for next-generation flexible and high-definition displays. However, perovskite QD films often suffer from low PLQYs due to the dynamic characteristics between the QD’s surface and organic ligands and inefficient elec. transportation resulting from long hydrocarbon organic ligands as highly insulating barrier, which impair the ensuing device performance. Here, a general organic-inorganic hybrid ligand (OIHL) strategy is reported on to passivate perovskite QDs for highly efficient electroluminescent devices. Films based on QDs through OIHLs exhibit enhanced radiative recombination and effective elec. transportation properties compared to the primal QDs. After the OIHL passivation, QD-based light-emitting diodes (QLEDs) exhibit a maximum peak external quantum efficiency (EQE) of 16.48%, which is the most efficient electroluminescent device in the field of perovskite-based LEDs up to date. The proposed OIHL passivation strategy positions perovskite QDs as an extremely promising prospect in future applications of high-definition displays, high-quality lightings, as well as solar cells. The experimental process involved the reaction of Indium(III) bromide(cas: 13465-09-3Recommanded Product: Indium(III) bromide)

Indium(III) bromide(cas: 13465-09-3) is used in organic synthesis as a water tolerant Lewis acid. It efficiently catalyzes the three-component coupling of β-keto esters, aldehydes and urea (or thiourea) to afford the corresponding dihydropyrimidinones.Recommanded Product: Indium(III) bromide

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

In 2018,Dubbu, Sateesh; Bardhan, Anirban; Chennaiah, Ande; Vankar, Yashwant D. published 《A Cascade of Prins Reaction and Pinacol-Type Rearrangement: Access to 2,3-Dideoxy-3C-Formyl β-C-Aryl/Alkyl Furanosides and 2-Deoxy-2C-Branched β-C-Aryl Furanoside》.European Journal of Organic Chemistry published the findings.Application of 13465-09-3 The information in the text is summarized as follows:

2,3-Dideoxy-3C-formyl β-C-aryl/alkyl furanosides were synthesized in a stereoselective manner through a cascade of Prins reaction and pinacol-type rearrangement of an -O-TBDPS protected homoallylic alc., derived from D-mannitol, and various carbonyl compounds Furthermore, this method was successfully applied to the synthesis of a fused-bicyclic β-C-aryl furanoside moiety and a 2,3-dideoxy-3C-Me β-C-aryl furanoside which are found in core structures of bioactive mols. Further, the strategy was extended to a silyl-Prins reaction for the synthesis of a 2-deoxy-2C-branched β-C-aryl furanoside. The experimental part of the paper was very detailed, including the reaction process of Indium(III) bromide(cas: 13465-09-3Application of 13465-09-3)

Indium(III) bromide(cas: 13465-09-3) is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells.Application of 13465-09-3

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

《Realizing Tunable White Light Emission in Lead-Free Indium(III) Bromine Hybrid Single Crystals through Antimony(III) Cation Doping》 was written by Li, Zhongyuan; Song, Gaomin; Li, Ye; Wang, Le; Zhou, Tianliang; Lin, Zheshuai; Xie, Rong-Jun. Safety of Indium(III) bromideThis research focused ontunable white light emission leadfree indium bromine hybrid crystal; antimony cation doping. The article conveys some information:

Low-dimensional metal halide hybrids (OIMHs) have recently been explored as single-component white-light emitters for use in solid-state lighting. However, it still remains challenging to realize tunable white-light emission in lead-free zero-dimensional (0D) hybrid system. Here, a combination strategy has been proposed through doping Sb3+ enabling and balancing multiple emission centers toward the multiband warm white light. We first synthesized a new lead-free 0D (C8NH12)6InBr9·H2O single crystal, in which isolated [InBr6]3- octahedral units are separated by large organic cations [C8NH12]+. (C8NH12)6InBr9·H2O exhibits dual-band emissions with one intense cyan emission and a weak red emission tail. The low-energy ultrabroadband red emission tail can be greatly enhanced by the Sb3+ doping. Exptl. data and first-principles calculations reveal that the original dominant cyan emission is originated from the organic cations [C8NH12]+ and that the broadband red emission is ascribed to self-trapped excitons in [In(Sb)Br6]3-. When the Sb concentration is 0.1%, a single-component warm white-light emission with a photoluminescence quantum efficiency of 23.36%, correlated color temperature of 3347 K, and a color rendering index up to 84 can be achieved. This work represents a significant step toward the realization of single-component white-light emissions in environmental-friendly, high-performance 0D metal halide light-emitting materials. After reading the article, we found that the author used Indium(III) bromide(cas: 13465-09-3Safety of Indium(III) bromide)

Indium(III) bromide(cas: 13465-09-3) is used in organic synthesis as a water tolerant Lewis acid. It efficiently catalyzes the three-component coupling of β-keto esters, aldehydes and urea (or thiourea) to afford the corresponding dihydropyrimidinones.Safety of Indium(III) bromide

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Nakao, Shuichi; Saikai, Miki; Nishimoto, Yoshihiro; Yasuda, Makoto published an article in 2021. The article was titled 《InBr3-Catalyzed Coupling Reaction between Electron-Deficient Alkenyl Ethers with Silyl Enolates for Stereoselective Synthesis of 1,5-Dioxo-alk-2-enes》, and you may find the article in European Journal of Organic Chemistry.Application In Synthesis of Indium(III) bromide The information in the text is summarized as follows:

A coupling reaction of electron-deficient alkenyl ethers with silyl enolates catalyzed by InBr3 was achieved. Various silyl enolates and 2-carbonylalkenyl ethers were applicable, giving the corresponding 1,5-dioxo-alk-2-enes with perfect stereoselectivity of the alkene moieties. The present coupling reaction proceeds via the 1,4-addition of silyl enolates to alkenyl ethers followed by elimination of silyl alkoxides, in which moderate-Lewis acidic InBr3 performs both the activation of alkenyl ethers and the elimination of alkoxy groups regardless of the presence of various coordinative functional groups. In addition to this study using Indium(III) bromide, there are many other studies that have used Indium(III) bromide(cas: 13465-09-3Application In Synthesis of Indium(III) bromide) was used in this study.

Indium(III) bromide(cas: 13465-09-3) is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells.Application In Synthesis of Indium(III) bromide

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

Product Details of 13465-09-3In 2018 ,《Indium(III) as π-acid catalyst for the electrophilic activation of carbon-carbon unsaturated systems》 appeared in Organic & Biomolecular Chemistry. The author of the article were Perez Sestelo, Jose; Sarandeses, Luis A.; Martinez, M. Montserrat; Alonso-Maranon, Lorena. The article conveys some information:

A review. This review focuses on the utilization of indium(III) as a π-acid for the activation of C-C unsaturated bonds in organic synthesis. In addition to its well-known σ-coordination with carbonyl derivatives, indium(III) undergoes efficient π-coordination with unsaturated systems to trigger nucleophilic addition Accordingly, indium(III) halides and salts (InX3, X = Cl, Br, I, OTf, ONf, NTf2) have been reported as useful catalysts for a broad range of carbon-carbon and carbon-heteroatom bond formation reactions, including hydrofunctionalization (hydroarylation, hydroamination, hydroalkoxylation, and hydrothiolation), enyne cycloisomerization, and related reactions. In these reactions the counterion has a significant effect on the catalytic activity, and the development of novel In(III) complexes and the generation of highly electrophilic cationic indium(III) species has increased its synthetic applications as a π-acid catalyst. The experimental process involved the reaction of Indium(III) bromide(cas: 13465-09-3Product Details of 13465-09-3)

Indium(III) bromide(cas: 13465-09-3) is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells.Product Details of 13465-09-3

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary

In 2018,Miranda, Silvia; Gomez, Ana M.; Lopez, J. Cristobal published 《Diversity-Oriented Synthetic Endeavors of Newly Designed Ferrier and Ferrier-Nicholas Systems Derived from 1-C-Alkynyl-2-deoxy-2-C-Methylene Pyranosides》.European Journal of Organic Chemistry published the findings.Recommanded Product: Indium(III) bromide The information in the text is summarized as follows:

Novel pyranose derivatives that display Ferrier- and Ferrier-Nicholas-like reactivity have been designed. These systems: 1-C-alkynyl-2-deoxy-2-C-methylene pyranosides (Ferrier), and their corresponding dicobalthexacarbonyl alkenyl derivatives (Ferrier-Nicholas), which can be accessed by a concise synthetic route from com. available tri-O-acetyl-D-glucal, allow the incorporation of two nucleophiles (at positions C-3 and C-2′) in the pyranose ring. The study of these systems has resulted in the discovery of novel reaction patterns that allow, among others, access to open-chain derivatives, branched pyranosides, 1,6-anhydro derivatives and, when reacting with indole, access to a new family of tetracyclic indole-containing carbohydrate derivatives, namely, cyclohepta[b]indole-fused glycals. The latter are, most likely, formed by a bis Ferrier-type rearrangement followed by an unusual intramol. 7-endo-dig Friedel-Crafts alkenylation of one of the indole moieties by the C-1 alkyne.Indium(III) bromide(cas: 13465-09-3Recommanded Product: Indium(III) bromide) was used in this study.

Indium(III) bromide(cas: 13465-09-3) is used as a catalyst to produce dithioacetals when unactivated alkynes react with thiols and fields such as optics and microelectronics that utilize semiconductor technology have wide uses for indium in high-performing solar cells.Recommanded Product: Indium(III) bromide

Referemce:
Bromide – Wikipedia,
bromide – Wiktionary