One prominent application of synthetic organobromine compounds is the use of polybrominated diphenyl ethers as fire-retardants, and in fact fire-retardant manufacture is currently the major industrial use of the element bromine. 90-59-5, formula is C7H4Br2O2, Name is 3,5-Dibromo-2-hydroxybenzaldehyde, COA of Formula: C7H4Br2O2
Li, Qiankun;Wang, Chaoqun;Mu, Hongliang;Jian, Zhongbao research published 《 A readily available neutral nickel catalyst for accessing linear ultrahigh molecular weight polyethylene in a living manner》, the research content is summarized as follows. It is of great importance and is highly desired in the olefin polymerization catalysis that a simple catalyst derived from cheap starting materials and short synthetic pathways exhibits superior catalytic property towards a polymerization reaction. In this contribution, starting from com. available and cheap materials, by using a short and simple three-step reaction route we report a readily available neutral phenoxy-imine nickel catalyst, which significantly enables the formation of linear ultrahigh mol. weight polyethylene (∼5 brs/1000C, Mn = 1531 kDa) in a living polymerization (PDI = 1.08-1.11). An enhancement of 77 times on the polymer mol. weight occurs compared to the classical 2,6-diisopropyl substituted phenoxy-imine nickel catalyst. This avoids a tedious synthetic procedure and the use of an excess aluminum reagent as the activator and the scavenger.
COA of Formula: C7H4Br2O2, 3,5-Dibromosalicylaldehyde reacts with alkyl cyanoacetates in the presence of ammonium acetate to yield 4H- chromenes.
3,5-Dibromosalicylaldehyde, also known as 3,5-Dibromosalicylaldehyde, is a useful research compound. Its molecular formula is C7H4Br2O2 and its molecular weight is 279.91 g/mol. The purity is usually 95%.
3,5-Dibromosalicylaldehyde reacts with alkyl cyanoacetates in the presence of ammonium acetate to yield 4H- chromenes. 3,5-Dibromosalicylaldehyde can be used in the synthesis of Schiff base and can be used as reactant for synthesis of Schiff base ligands which forms mononuclear complexes with copper(II), nickel(II), zinc(II) and cobalt(II).
3,5-Dibromosalicylaldehyde is a copper complex that has been synthesized from 3,5-dibromosalicylaldehyde and copper chloride. FTIR spectroscopy revealed that the coordination geometry of the copper complex is octahedral with two nitrogen atoms in the equatorial plane. The presence of hydrogen bonding interactions was confirmed by homologous protein adsorption experiments. This chemical structure was determined using X-ray crystallography and fluorescence probe experiments. The copper complex showed high affinity for malonic acid, which is an ester hydrochloride. The molecular mechanism of this interaction is based on adsorption, which occurs through hydrogen bonding interactions and hydrophobic interactions. Structural analysis revealed that the polymeric matrix consists of a three-dimensional network of crosslinked chains, while FTIR analysis indicated a possible disulfide bond between two cysteine residues., 90-59-5.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary