Xu, Jingwei published the artcileA Thioether-Catalyzed Cross-Coupling Reaction of Allyl Halides and Arylboronic Acids, Safety of 1-Bromo-4-fluoro-2-methylbenzene, the main research area is allyl benzene preparation; arylboronic acid allyl bromide cross coupling reaction thioether catalyst; Allylation; Cross-Coupling; Organocatalysis; Sulfide; Ylide.
Recent discovery of designer thioethers I (R = H, OMe, CF3; R1 = H, OMe, F, CF3; R2 = H, Me) as a highly active organocatalyst for reactions between allyl bromides e.g., 4-bromocrotonic acid Et ester and arylboronic acids R3B(OH)2 (R3 = Ph, 4-methoxyphenyl, 2,3-dihydrobenzo[b][1,4]dioxin-6-yl, etc.) was reported. The cross-coupling event occurred readily under mild condition in the presence of a weak inorganic base. Preliminary mechanistic studies suggested a sulfonium ylide mechanism.
Angewandte Chemie, International Edition published new progress about Aromatic compounds Role: SPN (Synthetic Preparation), PREP (Preparation). 452-63-1 belongs to class bromides-buliding-blocks, name is 1-Bromo-4-fluoro-2-methylbenzene, and the molecular formula is C7H6BrF, Safety of 1-Bromo-4-fluoro-2-methylbenzene.
Referemce:
Bromide – Wikipedia,
bromide – Wiktionary